For fans of the show, it was great to finally see those two characters come together as the chemistry between Melissa Benoist, 28, and Chris Wood, 28, has been sizzling hot all season long. And now we know why. According to Entertainment Tonight, Benoist and Wood's on-screen relationship has blossomed into a real, off-screen relationship as well. When Entertainment Tonight visited the Supergirl set last month, Wood gushed about working with Benoist. Website comicbook.com reports that this isn't the first time Benoist has fallen for someone she has worked with. She fell for Blake Jenner while working together on Glee. The two got married in the spring of 2015; however, this past December, she filed for divorce from him.